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101.
The objective of this study was to investigate whether 222Rn in groundwater can be used as a tracer for light non‐aqueous phase liquid (LNAPL) quantification at a field site treated by dual‐phase LNAPL removal. After the break of a pipeline, 5 ha of soil in the nature reserve Coussouls de Crau in southern France was contaminated by 5100 m3 of crude oil. Part of this oil seeped into the underlying gravel aquifer and formed a floating oil body of about 3.9 ha. The remediation consists of plume management by hydraulic groundwater barriers and LNAPL extraction in the source zone. 222Rn measurements were performed in 21 wells in and outside the source zone during 15 months. In uncontaminated groundwater, the radon activity was relatively constant and remained always >11 Bq/L. The variability of radon activity measurements in wells affected by the pump‐and‐skim system was consistent with the measurements in wells that were not impacted by the system. The mean activities in wells in the source zone were, in general, significantly lower than in wells upgradient of the source zone, owing to partitioning of 222Rn into the oil phase. The lowest activities were found in zones with high non‐aqueous phase liquid (NAPL) recovery. LNAPL saturations around each recovery well were furthermore calculated during a period of high groundwater level, using a laboratory‐determined crude oil–water partitioning coefficient of 38.5 ± 2.9. This yielded an estimated volume of residual crude oil of 309 ± 93 m3 below the capillary fringe. We find that 222Rn is a useful and cheap groundwater tracer for finding zones of good LNAPL recovery in an aquifer treated by dual‐phase LNAPL removal, but that quantification of NAPL saturation using Rn is highly uncertain.  相似文献   
102.
Natural Hazards - We perform numerical simulations to assess how coastal tsunami hazard from submarine mass failures (SMFs) is affected by slide kinematics and rheology. Two types of two-layer SMF...  相似文献   
103.
The standard model of caldera formation is related to the emptying of a magma chamber and ensuing roof collapse during large eruptions or subsurface withdrawal. Although this model works well for numerous volcanoes, it is inappropriate for many basaltic volcanoes (with the notable exception of Hawaii), as these have eruptions that involve volumes of magma that are small compared to the collapse. Many arc volcanoes also have similar oversized depressions, such as Poas (Costa Rica) and Aoba (Vanuatu). In this article, we propose an alternative caldera model based on deep hydrothermal alteration of volcanic rocks in the central part of the edifice. Under certain conditions, the clay-rich altered and pressurized core may flow under its own weight, spread laterally, and trigger very large caldera-like collapse. Several specific mechanisms can generate the formation of such hydrothermal calderas. Among them, we identify two principal modes: mode 1: ripening with summit loading and flank spreading and mode II: unbuttressing with flank subsidence and flank sliding. Processes such as summit loading or flank subsidence may act simultaneously in hybrid mechanisms. Natural examples are shown to illustrate the different modes of formation. For ripening, we give Aoba (Vanuatu) as an example of probable summit loading, while Casita (Nicaragua) is the type example of flank spreading. For unbuttressing, Nuku Hiva Island (Marquesas) is our example for flank subsidence and Piton de la Fournaise (La Réunion) is our example of flank sliding. The whole process is slow and probably needs (a) at least a few tens of thousands of years to deeply alter the edifice and reach conditions suitable for ductile flow and (b) a few hundred years to achieve the caldera collapse. The size and the shape of the caldera strictly mimic that of the underlying weak core. Thus, the size of the caldera is not controlled by the dimensions of the underlying magma reservoir. A collapsing hydrothermal caldera could generate significant phreatic activity and trigger major eruptions from a coexisting magmatic complex. As the buildup to collapse is slow, such caldera-forming events could be detected long before their onset.  相似文献   
104.
Previous time-lapse Electrical Resistivity Tomography (ERT) studies have experienced difficulties in reconstructing reliable calculated resistivity changes in the subsurface. Increases or decreases of resistivity appear in the calculated ERT image where no changes were noted in the subsurface, leading to erroneous hydrological interpretations of the geophysical results. In this article, we investigate how a variation of actual resistivity with time and at shallow depth can influence time-lapse ERT results and produce resistivity artefacts at depth. We use 1 and 2-D numerical modelling to simulate infiltration scenarios. Using a standard time-lapse inversion, we demonstrate the resistivity artefact production according to the electrode spacing parameter. We used an advanced inversion methodology with a decoupling line at shallow depth to attenuate or remove resistivity artefacts. We also applied this methodology to a field data set obtained in a semi-arid environment in Burkina Faso, West Africa. Here, time-lapse ERT shows several resistivity artefacts of calculated resistivity if a standard inversion is used. We demonstrate the importance of a dense sampling of shallow resistivity variations at shallow depth. Advanced interpretation allows us to significantly attenuate or remove the resistivity artefact production at intermediate depth and produce reliable interpretation of hydrological processes.  相似文献   
105.
Suspended sediments in fluvial systems originate from a myriad of diffuse and point sources, with the relative contribution from each source varying over time and space. The process of sediment fingerprinting focuses on developing methods that enable discrete sediment sources to be identified from a composite sample of suspended material. This review identifies existing methodological steps for sediment fingerprinting including fluvial and source sampling, and critically compares biogeochemical and physical tracers used in fingerprinting studies. Implications of applying different mixing models to the same source data are explored using data from 41 catchments across Europe, Africa, Australia, Asia, and North and South America. The application of seven commonly used mixing models to two case studies from the US (North Fork Broad River watershed) and France (Bldone watershed) with local and global (genetic algorithm) optimization methods identified all outputs remained in the acceptable range of error defined by the original authors. We propose future sediment fingerprinting studies use models that combine the best explanatory parameters provided by the modified Collins (using correction factors) and Hughes (relying on iterations involving all data, and not only their mean values) models with optimization using genetic algorithms to best predict the relative contribution of sediment sources to fluvial systems.  相似文献   
106.
Abstract

We impose a surface forcing on the 2D, Boussinesq, thermohaline equations in a rectangular domain, in the form of equatorially symmetric cosine distributions of salinity flux and temperature. This system may be seen as an idealization of the ocean thermohaline circulation on the global scale over intervals of centuries or millenia. Multiple steady states are found numerically. They reflect the competition between the opposite signs of the temperature and salinity-driven equatorially symmetric circulations. There are also pole-to-pole, equatorially asymmetric circulations. In the control space of the temperature and salinity-flux forcing amplitudes, these equilibria form two cusp catastrophes, and transitions between stable equilibria occur through several distinct bifurcations. These catastrophes can be reproduced in simple box models connecting stirred reservoirs through capillary pipes. This steady-state analysis may provide a framework for a better understanding of climatic transitions between different stable regimes of the ocean-atmosphere system.  相似文献   
107.
RÉSUMÉ

Les modèles pluie–débit sont fortement utilisés dans la gestion des risques hydrologiques et la prévision des crues. Dans cette étude, nous présentons un modèle pluie–débit pour la prévision des débits horaires basé sur la technique des réseaux de neurones artificiels (RNA). Ce modèle a été développé et appliqué sur le bassin versant de l’Eure au Nord-Ouest de la France afin de dépasser les problèmes dus à la non-linéarité de la relation pluie–débit et à l’imprécision des données collectées. La création de ce modèle a nécessité plusieurs étapes pendant lesquelles nous avons pu déterminer les paramètres du modèle permettant la compréhension de la complexité hydrologique et la production des informations nécessaires à la prévision. Elles ont abouti à un modèle de réseau de neurones artificiels capable d’effectuer, en quelques secondes, des prévisions des crues efficaces jusqu’à un horizon de prévision de 48 h. Ces résultats confirment que les modèles RNA peuvent jouer un rôle important dans le domaine de la prévision car capables de modéliser la non-linéarité des relations pluie–débit rencontrées sur certains bassins hydrologiques.
Editor Z.W. Kundzewicz Associate editor E. Gargouri  相似文献   
108.
Understanding the mobility of chemical elements during fluid–rock interactions is critical to assess the geochemical evolution of a rock undergoing burial and metamorphism and, more generally, to constrain the geochemical budget of the subduction factory. In particular, determining the behavior and mobility of Ti in aqueous fluids constitutes a great challenge that is still under scrutiny. Here, we study plant fossils preserved in blueschist metasedimentary rocks from the Marybank Formation (New Zealand). Using scanning and transmission electron microscopies (SEM and TEM), we show that the carbonaceous material (CM) composing the fossils contains abundant nano-inclusions of Ti- and Fe-oxides. These nanocrystals are mainly anatase, rutile, and Fe–Ti oxides. The mineral composition observed within the fossils is significantly different from that detected in the surrounding rock matrix. We propose that Ti and Fe might have been mobilized by the alteration of a detrital Ti–Fe-rich protolith during an early diagenetic event under acidic and reducing conditions. Aqueous fluids rich in organic ligands released by the degradation of organic matter may have been involved. Moreover, using mass balance and petrological observations, we show that the contrasted mineralogy between the rock matrix and the fossil CM might be the consequence of the chemical isolation of fossil CM during the prograde path of the rock. Such an isolation results from the early formation of quartz and Fe-rich phyllosilicate layers enclosing the fossil as characterized by SEM and TEM investigations. Overall, this study shows that investigating minerals associated with CM down to the nanometer scale in metamorphic rocks can provide a precious record of early prograde geochemical conditions.  相似文献   
109.
Granite magma migration and emplacement along thrusts   总被引:1,自引:0,他引:1  
This paper investigates the influence exerted by brittle tectonic structures in the emplacement of granite plutons in contractional settings. We address both cases where contractional tectonics and magma intrusion are (1) coeval, to study how active contractional tectonics controls the transport of magma, and (2) diachronous, to study the role of pre-existing structures on the transport of magma. In light of new experimental models, we show that magma can rise along thrusts ramps and flats. This phenomenon occurs for both low-viscosity magma (basalts to andesite) and high-viscosity magma (dry granite). The experimental results also allow the evaluation of the role played by magma viscosity in determining pluton geometries. In addition, a review of literature demonstrates a spatial and causal relationship between granites and thrusts and highlights the geometric control of magma pathways in the pluton final shape. The abundance of subhorizontal and tabular granitic intrusions indicates that the location of inflating granitic sills along thrust flats can be common. We argue that active and pre-existing flats-and-ramps thrusts provide a preferential continuous planar anisotropy susceptible to become a granitic magma migration pathway.  相似文献   
110.
The turbulent characteristics of the neutral boundary layer developing over rough surfaces are not well predicted with operational weather-forecasting models. The problem is attributed to inadequate mixing-length models, to the anisotropy of the flow and to a lack of controlled experimental data against which to validate numerical studies. Therefore, in order to address directly the modelling difficulties for the development of a neutral boundary layer over rough surfaces, and to investigate the turbulent momentum transfer of such a layer, a set of hydraulic flume experiments were carried out. In the experiments, the mean and turbulent quantities were measured by a particle image velocimetry (PIV) technique. The measured velocity variances and fluxes \({(\overline{{u_{i}^{\prime}}{u_{j}^{\prime}}})}\) in longitudinal vertical planes allowed the vertical and longitudinal gradients (?/?z and ?/?x) of the mean and turbulent quantities (fluxes, variances and third-order moments) to be evaluated and the terms of the evolution equations for ?e/?t, \({\partial \overline{u^{\prime 2}}/\partial t}\), \({\partial \overline{w^{\prime 2}}/\partial t}\) and \({\partial \overline{{u^{\prime}}{w^{\prime}}}/\partial t}\) to be quantified, where e is the turbulent kinetic energy. The results show that the pressure-correlation terms allow the turbulent energy to be transferred equitably from \({\overline{{u^{\prime}}^{2}}}\) to \({\overline{{w^{\prime}}^{2}}}\). It appears that the repartition between the constitutive terms of the budget of e, \({\overline{{u^{\prime}}^{2}}}\), \({\overline{{w^{\prime}}^{2}}}\) and \({\overline{{u^{\prime}}{w^{\prime}}}}\) is not significantly affected by the development of the rough neutral boundary layer. For the whole evolution, the transfers of energy are governed by the same terms that are also very similar to the smooth-wall case. The PIV measurements also allowed the spatial integral scales to be computed directly and to be compared with the dissipative and mixing length scales, which were also computed from the data.  相似文献   
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